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Set # 5 was issued in 2007, contains 26 cards, and features St. Matthew, St. Francis Xavier, All Saints Day and The Conversion of St. Paul. The cards also display beautiful religious art from classical artists such as Raphael, Giotto, Murrillo, Reni, Lippi, Fra Angelico, Zurbaran, and Saraceni.
The cards of Set #5 with Feast Date:
| All Saints Day | November 1 |
| St. Andrew | November 30 |
| Feast of the Archangels | September 29 |
| St. Anthony | January 17 |
| Nativity of Mary | September 8 |
| St. Cecilia | November 22 |
| The Conversion of St. Paul | January 25 |
| St. Denis | October 9 |
| St. Francis Xavier | December 3 |
| Holy Family | Special |
| Holy Innocents | December 28 |
| Martyrs of Japan | February 6 |
| St. Jerome | September 30 |
| St. Leander | February 27 |
| St. Leo the Great | November 10 |
| St. Lucy | December 13 |
| St. Luke | November 18 |
| St. Margaret of Cortona | February 22 |
| St. Margaret of Scotland | November 16 |
| St. Matthew | September 21 |
| Our Lady of Sorrows | September 14 |
| St. Peter Canisius | December 21 |
| The Presentation of Our Lord | February 2 |
| St. Raymond Penyafort | January 7 |
| St. Ursula | October 21 |
| St. Valentine | February 14 |
